화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.1914
발표분야 재료
제목 Synthesis of Metal-Incorporated Cadmim Chalcogenide Heterostructured Nanocrystals with Different Morphologies
초록 Colloidal heterostructured hybrid nanomaterials are of great interest due to the synergistic properties originating from different types of metal-semiconductor interfaces and thus lead to various applications such as photocatalysts, bioimaging and so forth. Here, we report on the synthesis of metal-semiconductor hybrid nanomaterials, more specifically platinum-tipped or -decorated cadmium chalcogenide nanocrystals with different morphologies including nanorods and tetrapods. Depending on the surface conditions of semiconductor nanocrystals, platinum metals nucleate and grow from either one- or both ends of semiconductor nanocrystals or all around the nanocrystal surface. We further demonstrate the incorporation of cobalt and cobalt oxide nanoparticles onto the platinum-tipped CdSe@CdS hybrid nanorods, where the terminal platinum NP tips selectively seed the growth of metal cobalt NP tips as either nano-matchsticks with one metal tip or dumbbells with two metal tips at both ends of nanorods. These hybrid nanorods show differeny self-assembly structures depending on the nature of nanorod or tetrapod metallic NP inclusions.
저자 성영훈1, 임재훈2, Lawrence J. Hill3, Jeffrey Pyun3, 차국헌1
소속 1서울대, 2Los Alamos National Laboratory, 3Univ. of Arizona
키워드 Nanocrystals; Hybrids; Heterostructures
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