| 학회 |
한국고분자학회 |
| 학술대회 |
2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO)) |
| 권호 |
44권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Crosslinked solid electrolytes without solvent for lithium battery. |
| 초록 |
Ultraviolet (UV) curable electrolyte has received attention as a replacement of liquid electrolytes due to chemical stability. Flexible polymer electrolytes are fabricated by poly(ethylene glycol) dimethacrylate and methacrylamide based monomer. We are trying to make a polymer electrolyte with lithium cations directly attached to the monomer of the electrolyte rather than the lithium cation substituted of the polymer electrolyte due to the impregnation. Fluorosulfonyl isocyanate (FSO2NCO) was used to synthesize reactive FSI-type materials. This could expect a high ionic conductivity due to electron attractor effect. A polymer with a lithium cation has a hydrophilic group in the polymer matrix and can form a wide channel that smoothly moves the lithium cation. The isocyanate reacted with methacrylamide to form a urea structure. We studied the fundamental for Li battery. FT-IR, photo-DSC, TGA and 1H NMR spectroscopy are employed to characterize the electrolytes. |
| 저자 |
이승찬, 윤수진, WEI ZHANG, 최인환, 김재웅, 마붑, 김환기
|
| 소속 |
건국대 |
| 키워드 |
Polymer electrolytes; Li-ion battery
|
| E-Mail |
|
