화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 봄 (04/23 ~ 04/25, 창원컨벤션센터)
권호 20권 1호, p.531
발표분야 에너지
제목 Lithium Battery Using Porous Carbon/Sulfur Composite Cathode
초록 Sulfur (S) has many valuable characteristics, such as a low equivalent weight, extremely low cost, and nontoxicity. In a Li-S cell, the potential corresponds to 1/2 ~ 2/3 of the potential exhibited by a typical positive electrode for a Li-ion cell (3.2 V ~ 4.2 V). However, this low potential is outweighed by the 1672 mA h g-1 theoretical specific capacity, which is the highest of all known solid cathode materials. To improve the electrochemical performance of Li-S rechargeable batteries, tunable porous carbon materials, which are known as carbide-derived carbons (CDCs), are employed as adsorbents and conductive matrices for the cathodic sulfur materials. A new assembly for Li-S cells was developed by introducing multi-layer membranes as separators. The utilization of the multi-layer membranes enables the minimization of the shuttle effect by expanding the distance between the separators and blocking the penetration of the polysulfide.
저자 연순화1, 김지은1, 안욱2, 임성남3, 신경희1
소속 1한국에너지기술(연), 2연세대, 3한국과학기술원
키워드 리튬전지; 리튬황전지; 다공성 카본; 분리막
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