화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 37권 2호
발표분야 첨단 산업용 고분자 소재
제목 Synthesis and Properties of a HNTs-based Fluorescent Nanohybrid by the combination of Surface-Initiated RAFT Polymerization and Coordination Chemistry
초록 A fluorescent nanohybrid complex comprising of halloysite nanotubes (HNTs), poly(2-hydroxyethyl methacrylate) (PHEMA), and europium ions (Eu3+) was successfully synthesized by the combination of surface-initiated reversible addition-fragmentation chain transfer (SI-RAFT) polymerization and coordination chemistry. The structure, morphology and fluorescence properties of the Eu3+ coordinated complexes were investigated by respective physical and spectral studies. FT-IR, XPS, FE-SEM and EDS analyses suggested the formation of the HNTs-g-PHEMA-Eu3+ nanohybrids. TGA scans further demonstrated the grafting of PHEMA on HNTs surface. The optical properties of HNTs-g-PHEMA-Eu3+ nanohybrids complex were investigated by fluorescence spectroscopy.
저자 Long Giang Bach, Md. Rafiqul Islam, 임권택
소속 부경대
키워드 nanohybrid complex; SI-RAFT
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