| 학회 |
한국공업화학회 |
| 학술대회 |
2005년 가을 (10/28 ~ 10/29, 건국대학교) |
| 권호 |
9권 2호 |
| 발표분야 |
촉매 |
| 제목 |
SYNTHESIS OF 5-MEMBERED CARBONATE FROM VCHO AND CO2 USING IONIC LIQUID |
| 초록 |
The synthesis of 5-membered carbonate from 4-vinyl-1-cyclohexene-1,2-epoxide(VCHO) and carbon dioxide was performed without using any solvent in the presence of ionic liquid as catalyst. The reaction was carried out in a batch autoclave reactor. The conversion of VCHO was affected by the structure of the ionic liquid ; the one with the cation of bulkier alkyl chain length and with more nucleophilic anion showed better reactivity. The conversion of VCHO increased as the temperature increased from 60℃ to 140℃ probably due to the increase of the absorption of carbon dioxide into the mixture of VCHO and the ionic liquid. |
| 저자 |
이은하, 박대원, 문나영, M.D. Manju, 김경훈
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| 소속 |
부산대 |
| 키워드 |
VCHO; CO2; ionic liquid
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| E-Mail |
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