| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
22권 2호 |
| 발표분야 |
콜로이드.계면화학_포스터 |
| 제목 |
Synthesis of Metallosupramolecular Nanocages through the Assembly of Triple-Stranded Helicates. |
| 초록 |
Triple-stranded helicates-based metallosupramolecular nanocages are susccessfully synthesized through unique multiple assembly strategy. The prepared discrete molecular nanocages are considered the assembly of six triple-stranded helicates interconnected by four metallic junctions. These are unusual examples of a highly symmetric discrete molecular architectures, resulting from the coordination-driven assembly of in-situ generated modules. The right- and left-handed triple-stranded helicates, structurally analogous to the basic building blocks in molecular nanocages can be synthesized in separated reactions. Owing to the presence of structurally well-defined, highly systematic, and robust cavities of the synthesized cages, the molecular nanocage shows much higher CO2 capture capacity and selectivity compared with the triple-stranded helicates and other single molecules. |
| 저자 |
HO VAN MINH HAI, MAI DUY HIEN, 유효종
|
| 소속 |
한림대 |
| 키워드 |
Discrete Molecular Cage; Triple-Stranded Helicate; Tertiary Assembly; Selective CO2 Uptake |
| E-Mail |
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