화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터)
권호 25권 2호, p.1673
발표분야 에너지 환경 (Energy and Environment)
제목 Effect of heterometallic homogeneous electron mediators on continuous N2O gas removal: An electrochemical and electroscrubbing
초록 N2O gas removal generally done by high temperature catalytic process. Here in, a room temperature electroscrubbing method was developed to remove N2O gas. A combination of homogeneous mediator precursors such as [Ni(II)(CN)4]2-+[Fe(II)(CN)6]4-, [Ni(II)(CN)4]2-+[Fe(III)(CN)6]3-, [Co(II)(CN)5]3+[Fe(III)(CN)6]3-, and Ni[Co(II)(CN)5]1- were used to evaluate the N2O gas removal. Based on the ORP (oxidation/reduction potential) value, an active low velant ion in the heteromatellic complex was identified, which was then correlated with UV-visible spectral results. Through the difference in  inline FTIR gas analyzer results, selected the effective heterometallic homogeneous electron mediator on N2O removal.  

Keywords: N2O removal, MER, heteometallic electron mediators, Electro-scrubbing  
저자 문일식, A.G. Ramu, G. Muthuraman
소속 순천대
키워드 에너지 환경
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