학회 | 한국화학공학회 |
학술대회 | 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터) |
권호 | 25권 2호, p.1673 |
발표분야 | 에너지 환경 (Energy and Environment) |
제목 | Effect of heterometallic homogeneous electron mediators on continuous N2O gas removal: An electrochemical and electroscrubbing |
초록 | N2O gas removal generally done by high temperature catalytic process. Here in, a room temperature electroscrubbing method was developed to remove N2O gas. A combination of homogeneous mediator precursors such as [Ni(II)(CN)4]2-+[Fe(II)(CN)6]4-, [Ni(II)(CN)4]2-+[Fe(III)(CN)6]3-, [Co(II)(CN)5]3+[Fe(III)(CN)6]3-, and Ni[Co(II)(CN)5]1- were used to evaluate the N2O gas removal. Based on the ORP (oxidation/reduction potential) value, an active low velant ion in the heteromatellic complex was identified, which was then correlated with UV-visible spectral results. Through the difference in inline FTIR gas analyzer results, selected the effective heterometallic homogeneous electron mediator on N2O removal. Keywords: N2O removal, MER, heteometallic electron mediators, Electro-scrubbing |
저자 | 문일식, A.G. Ramu, G. Muthuraman |
소속 | 순천대 |
키워드 | 에너지 환경 |
원문파일 | 초록 보기 |