| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO)) |
| 권호 |
22권 1호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Ring type in-situ flow electrochemical sensor for electrogenerated Ni(I) at 10 M KOH solution: An initial electrochemical study |
| 초록 |
Besides electrochemical sensor development for neutral and less supporting electrolyte concentrations, an electrochemical sensors for high concentrated supporting electrolyte medium is worth to discover due to unavailability. Here in, we have initiated to monitor the electrochemically prepared mediator [N(I)(CN)4]3- by in-situ flow sensor cell coupled with paired electrolysis cell. First, cyclic voltammetry peak current for a standard redox couple Fe(II)/Fe(III) with different concentration ratios was used in the flow sensor cell to check the developed method. Then the Chemically prepared [Ni(I)(CN)4]3- in presence of 10 M KOH at different concentrations were analyzed by UV-Visible and potentiometric titration method and compared. Finally, the chemically prepared different concentration of NI(I) do monitored using selected electrode under the inert atmosphere by flow sensor cell. The resulted calibration plot used to derive the concentration of [Ni(I)(CN)4]3-. |
| 저자 |
PERUMAL SILAMBARASAN, G.MUTHURAMAN, 문일식
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| 소속 |
순천대 |
| 키워드 |
Macro sensor; In-situ flow cell; high concentrated supporting electrolyte; mediator monitoring
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| E-Mail |
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