| 학회 |
한국고분자학회 |
| 학술대회 |
2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터) |
| 권호 |
43권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis of Bottlebrush Block Copolymers from Polystyrene and Poly (methyl methacrylate) Derivatives End-capped with Norbornene and Their Self-Assembly |
| 초록 |
Bottlebrush copolymers(BBCPs) are comblike macromolecules containing high density of polymeric side chains. Living anionic polymerization (LAP) is best polymerization technique for preparing well-defined macromonomers with predictable molecular weight(MW) and narrow molecular weight distributions (MWDs). The bottlebrush copolymers containing polystyrene and poly (methyl methacrylate) derivatives were prepared by combination of LAP and ROMP with grafting-through strategy. ω-End-nobornyl polystyrene and poly (methyl methacrylate) derivatives macromonomers were synthesized by LAP and brush homopolymers of resulted all macromonomers were synthesized by ROMP. Bottlebrush copolymers were obtained symmetrically by ROMP with ultrahigh MWs (Mw ~ 3558 kDa) and narrow MWDs (Ɖ ~ 1.17) in high conversions. The self-assembly of resulting BBCPs through solvent evaporation and post annealing revealed periodic lamellar morphologies and their structural colors. |
| 저자 |
서호빈, 유용군, 채창근, 김명진, 박인규, Mallela Yadagiri Lakshmi Narasimha Kishore, 이재석
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| 소속 |
광주과학기술원 |
| 키워드 |
anionic polymerization; ROMP; norbornene; bottlebrush polymers; photonic crystals
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| E-Mail |
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