| 학회 |
한국화학공학회 |
| 학술대회 |
2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔) |
| 권호 |
12권 1호, p.186 |
| 발표분야 |
미립자공학 |
| 제목 |
Photocatalytic Reduction of NO in the Absence and Presence of Hydrocarbons over Ti-, V-, Mo-MCM-41 |
| 초록 |
The photocatalytic reduction of NO into N2 in the absence and presence of hydrocarbons were investigated on Ti-, V-, and Mo-MCM-41 mesoporous molecular sieves. It was found that Ti-MCM-41 shows much higher photocatalytic reactivity for the direct decomposition of NO into N2 and O2 than V- and Mo-MCM-41. In contrast to Ti-MCM-41, the reactions of NO into N2 on V- and Mo-MCM-41 were remarkably enhanced in the co-existence of propane. From photoluminescence, ESR, and photo-adsorption measurements, the origin of the sharp difference observed on Ti-MCM-41 as compared to V- and Mo-MCM-41 in this reaction could be attributed to the low reactivity of the charge transfer excited Ti-oxide species for the activation of propane as the first step of the reduction of NO with propane. |
| 저자 |
홍승태1, 박달령2, 유승준3, 박형상1, Masakazu Anpo4
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| 소속 |
1서강대, 2한국가스공사, 3서남대, 4오사카부립대 |
| 키워드 |
Photocatalyst; NO reduction; MCM-41
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| E-Mail |
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| 원문파일 |
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