| 학회 |
한국고분자학회 |
| 학술대회 |
2008년 가을 (10/09 ~ 10/10, 일산킨텍스) |
| 권호 |
33권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Sulfonation of Poly(vinylbenzyl chloride)-grafted FEP Membranes |
| 초록 |
A two-step reaction (substitution reaction using thiourea to form thiourenium salt and a subsequent oxidation using hydrogen peroxide) was successfully applied to modify the benzylic chloride moiety of PVBC (Polyvinylbenzyl chloride)-grafted FEP membranes to a benzylic sulfonic acid moiety. Several attempts using sulfite ions failed due to the low reactivity of the sulfite ion with the membranes. The sulfonation was confirmed by FTIR, TGA, and SEM-EDX. Ion exchange capacity (IEC) and the degree of sulfonation (DOS) were also measured. |
| 저자 |
경비, 강성아, 고범석, 신준화, 노영창, 강필현
|
| 소속 |
한국 원자력(연) |
| 키워드 |
Membrane; Sulfonation; Poly(vinylbenzyl chloride); Radiation Graft |
| E-Mail |
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