화학공학소재연구정보센터
학회 한국재료학회
학술대회 2006년 봄 (05/19 ~ 05/20, 경상대학교 )
권호 12권 1호
발표분야 나노 및 생체재료
제목 Luminescence Properties of Er3+ doped YbPO4/YbPO4 Core/Shell Nanoparticles
초록 Er3+ doped YbPO4 nanoparticles capped with ligand, which provide a rigid crystal environment for the dopant ions and can be easily dispersed without agglomeration in organic solvent, may be considered as active components in light-emitting devices, low-threshold lasers, optical amplifiers, and for the labeling of biomolecules. However, it is reported that the quantum efficiency of Er3+ doped YbPO4 nanoparticles is still low. It is attributed to the energy-loss occurred by high energy vibration of organic ligands and OH group adsorbed at the particle surface. In this work, to enhance the quantum efficiency of Er3+ doped YbPO4 nanoparticles, Er3+ doped YbPO4/YbPO4 core/shell nanoparticles were synthesized by the solution method using a high boiling coordinating solvent. The crystallinity and morphology of Er3+ doped YbPO4/YbPO4 core/shell nanoparticles were investigated by XRD and TEM. The photoluminescence spectroscopic studies of the Er3+ doped core/shell nanoparticles were performed. Also, the luminescence lifetime and the quantum yield of the Er3+ emission were measured.
저자 Mi Ae Lim1, Sang Il Seok2, In chan Baek1, Bok Yeop Ahn2, Sunirmal Jana1, Nimai Chand Pramanik2, Seok In Hong1
소속 1Advanced Materials Division, 2Korea Research Institute of Chemical Technology
키워드 YbPO4; core/shell; luminescence
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