화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO))
권호 44권 1호
발표분야 기능성 고분자
제목 The Change of Cathode Buffer Layer's Contact Property based on Hydroxyl Position of Pyridine Derivatives in Organic Solar Cells
초록 The interface engineering is essential prerequisites for high-efficiency organic solar cells (OSCs). A modification of the interface holds promise for many tunable contact properties. Especially, the modification between a cathode buffer layer and an active layer can tune the contact property from ohmic to rectifying by introducing materials with a dipole. In this study, hydroxide substituted-pyridine derivatives, named 2-hydroxypyridine (2-OH-Py) and 4-hydroxypyridine (4-OH-Py), were inserted with a device configuration of ITO/ZnO/x-OH-Py/PTB7:PC71BM/MoO3/Ag, in which x means 2 or 4. An interface dipole difference, induced by the other position of the hydroxy group, was showed apparently in the efficiency of the OSCs. A power conversion efficiency (PCE) of 2-OH-Py reached up to 7.61%, while the rest one was only up to 4.69%. The work function of the modified interface also showed the results which have the same tendency with PCE.
저자 진호철, 정미진, 이준호, Sabrina Aufar Salma, Ratna Dewi Maduwu, 김주현
소속 부경대
키워드 Cathode Buffer Layer; Contact Property; Hydroxyl Position; Organic Solar Cells
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