| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
MMA Polymerization of Generation of Activators by Monomer Addition (GAMA) ATRP in the Presence of ppm Amount of Fe (III) Catalyst with Phosphorus Containing Ligands |
| 초록 |
MMA (methyl methacrylate) polymerization via generation of activators by monomer addition (GAMA) for atom transfer radical polymerization (ATRP) has been examined in the presence of a reduced amount of catalyst with various phosphorus containing ligands. In every instance of their ATRP behavior studies, most of these systems were well controlled. Phosphorus ligands such as DPMPP (diphenyl-(2-methoxy phenyl) phosphine), DPPP (2-(diphenylphosphino) pyridine), DPPB (2-(diphenylphosphino) benzaldehyde), TPP (Triphenyl-phosphine) were applied for the Fe(III)-mediated GAMA ATRP system. Among the ligands investigated, DPMPP is the best phosphorus ligands to ppm amount of Fe-catalyzed system. The polymerizations demonstrated the features of ‘‘living’’/controlled free-radical polymerization, such as the numberaverage molecular weights increasing linearly with monomer conversion and narrow molecular weight distributions (Mw/Mn＜1.3), even well if the amount of Fe (III) is as low as 10ppm. |
| 저자 |
진상웅, 하단, Mohd Yusuf Khan, 노석균, 류원석
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| 소속 |
영남대 |
| 키워드 |
GAMA ATRP; PPM AMOUNT
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| E-Mail |
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