화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터)
권호 22권 2호, p.2044
발표분야 환경
제목 TiO2 cathode for selective generation of Cu1+ in CuII[NiII(CN)4] towards gaseous CF4 removal in an electro-scrubbing
초록 The present investigation focuses on removal of gaseous CF4 using electrogenerated Cu(I)[Ni(II)(CN)4]1- in KOH medium.  At a first sight, the following figure shows the reduction of Cu2+ and Ni2+ selectively on TiO2 electrode through their oxidation/reduction potential (ORP) during electrolysis. On the basis of this result, Cu2+ can be reduced to Cu1+ and its electrocatlytic remvoval of CF4 was investigated. Additionally, with the help of reduction efficiency, CV and online FTIR analyzer, results, the removal of CF4 was confirmed.



Key words: Homogeneous mediator, Ni(II)(CN)42-, MER, degradation, Gaseous CF4.
저자 A.G.Ramu, Muthuraman Govindan, 문일식
소속 순천대
키워드 친환경; 고효율; 친환경 공정
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