화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2010년 봄 (05/13 ~ 05/14, BEXCO(부산))
권호 14권 1호
발표분야 촉매
제목 Hydrosilylation of Olefin with Hydrosilanes Catalyzed by SaturatedN-Heterocyclic Carbene Pt Complex
초록 Hydrosilylation, which is one of the most common method to synthesize a variety of organosilicon compounds can be catalyzed by group 10 metal complexes. Recently, we have synthesized new types of saturated N-heterocyclic carbene Pt(DVTMS) complexes with various substituents (Me, i-Pr, c-Hx). This complex has been employed to the reaction of olefin with hydrosilane and compared with commercialized Karstedt's catalyst. In this presentation, we will discuss a synthesis of saturated NHC-Pt catalyst and compare Karstedt's catalyst system with NHC-Pt catalyst each.
저자 유장현1, 한준수1, 황영애2, 유복렬1
소속 1한국과학기술(연), 2상명대
키워드 Hydrosilylation; Karstedt's cat.; NHC Pt cat.
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