초록 |
Hydrosilylation, which is one of the most common method to synthesize a variety of organosilicon compounds can be catalyzed by group 10 metal complexes. Recently, we have synthesized new types of saturated N-heterocyclic carbene Pt(DVTMS) complexes with various substituents (Me, i-Pr, c-Hx). This complex has been employed to the reaction of olefin with hydrosilane and compared with commercialized Karstedt's catalyst. In this presentation, we will discuss a synthesis of saturated NHC-Pt catalyst and compare Karstedt's catalyst system with NHC-Pt catalyst each. |