화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2008년 봄 (05/09 ~ 05/10, 한양대학교(안산))
권호 12권 1호
발표분야 촉매
제목 Selective catalytic reduction of NO by CO over Pt/WO3/CeO2/ZrO2 catalysts
초록 Various supported Pt catalysts (Pt/WO3/CeO2/ZrO2; Pt/ZrO2, Pt/CeO2, Pt/CeZrO, Pt/WO3/ZrO2, and Pt/WO3/CeZrO) were prepared and characterized, and their characteristics of catalytic reductions of NO by CO with or without oxygen were investigated. For NO CO reaction without oxygen, the easily reducible catalysts (Pt/CeO2 and Pt/CeZrO) exhibited better catalytic performances. With excess oxygen, however, Pt/WO3/CeZrO and Pt/WO3/ZrO2 catalysts exhibited higher NO conversions to N2 and N2O especially at a low temperature. The acidity in Pt/WO3/CeO2/ZrO2 catalysts should play an important role on their NO conversion only in the presence of excess oxygen.
저자 김정랑, Hai-ou Zhu, 임선기
소속 KAIST
키워드 Pt; CeO2; ZrO2; CeO2-ZrO2; precipitation; WO3; NO-CO reaction; excess oxygen; acidity
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