화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 봄 (04/04 ~ 04/06, 대전컨벤션센터)
권호 43권 1호
발표분야 분자전자 부문위원회 I
제목 Control of Fluoride Contents in Naphthalenediimide-Based Polymers toward Air Stable Transistors
초록 The developments in the organic material synthesis of versatile conjugated polymers have made magnificent improvements toward noteworthy features in organic field-effect transistors(OFETs). Among the high-performing conjugated building units, naphthalenediimide (NDI)-containing polymers show high electron transporting property with high co-planarity, boosting the growth in n-channel OFETs. However, to realize the commercial validity of the n-channel OFETs, NDI polymers should be necessary to possess the operating stability under the severe atmosphere including high-temperature, air, and moisture stabilities to oxidizing agents such as O2 or H2O. Herein, we present a molecular synthetic strategy for high air stability by controlling the degree of fluoride contents within the NDI-containing polymer, being one step ahead further toward commercialization.
저자 조용준1, 정아영2, 오준학2, 양창덕1
소속 1UNIST, 2POSTECH
키워드 naphthalenediimide; random conjugated polymers; fluoride-substituted bithiophene; air stability; organic field effect transistors
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