| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Synthesis, characterization and ethylene oligomerization studies of Ni(II) complexes ligated by [1-(1-alkyl-1H-benzoimidazol-2-yl)-alkyl-methylidene]-aryl amines |
| 초록 |
The design and synthesis of efficient transition metal complex catalysts that precisely control olefin coordination polymerization and oligomerization attracted considerable interest recently. In that aspect, we have designed and synthesized a new series of Ni(II) complexes based on (benzimidazolyl-alkyl-methylidene)-aryl amines ligands. The ligands were synthesized by condensation between benzoimidazolyl-alkyl-methanones and corresponding 2, 6-dialkyl substituted anilines. Variations in the electronic nature of ligands were achieved by N-alkylation of the benzimidazol ring. The complexes showed productivity in excess of 1.6 x 106 g oligomer per mol Ni-1 h-1 towards ethylene oligomerization on activation with ethylaluminum sesquichloride producing butenes as the major product (~ 90%) along with the formation of hexenes(~10%) |
| 저자 |
류인산1, 비누2, 김일1
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| 소속 |
1부산대, 2합성고분자 생물접합 하이브리드 재료사업단 |
| 키워드 |
bidentate ligand; ethylene oligomerization，Ni(II) complex; olefin; transition metal catalysts
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| E-Mail |
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