화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2008년 봄 (05/09 ~ 05/10, 한양대학교(안산))
권호 12권 1호
발표분야 촉매
제목 Autothermal reforming of propane over Ni/perovskite supported on Mo modified Catalysts
초록 Perovskite catalysts with a general formula of ABO3 exhibit high thermal stability and high oxygen storage capacity. A site metal in perovskite structure has a strong effect on thermal stability, while B site metal in perovskite structure acts active site. And it is well known that Mo metal is important material of Water Gas Shift reaction and Hydrogen production. So, to find optimum ratio of Mo, various ratio of Mo modified Ni/perovskite catalysts were tested. In this study, Mo modified Ni/perovskite catalysts were prepared by citric acid method of Sol-gel method. Ni(10wt%)-Mo(Xwt%)/LaFe0.5Ni0.5O3 perovskite catalysts (X=1, 5, 10,) were tested in constant pressure flow reactor with the reactant ratio of H2O/C3H8/O2=8.96/1.0/1.1. XRD, TGA, TEM and SEM were used to investigate morphologic construction, carbon deposition analysis, respectively.
저자 정길영1, 문동주2, 김종호1, 박남국1, 신재순1, 김영철1
소속 1전남대, 2한국과학기술(연)
키워드 Autothermal reforming; Water Gas Shift reaction; perovskite
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