학회 | 한국화학공학회 |
학술대회 | 2018년 봄 (04/25 ~ 04/27, 창원컨벤션센터) |
권호 | 24권 1호, p.883 |
발표분야 | 촉매 및 반응공학 |
제목 | PdM(Cu,Ni,Co,Fe)/ZnO catalysts for CO2 hydrogenation to methanol |
초록 | In recent years the effects of global warming have attracted efforts to cope with the rising level of CO2 in the atmosphere by capture, storage and utilisation of this abundant carbon source. One such effort is the transformation CO2 to methanol synethesis. Methanol from CO2 hydrogenation was industrially produced under high temperature and high pressure (523–573K, 3-5MPa), mainly using Cu/ZnO/Al2O3 catalysts. However, the efficiency of methanol synthesis was severely limited by thermodynamics because methanol synthesis was an exothermic reaction. Therefore, developing a low-temperature catalysts for methanol synthesis will greatly reduce the production cost. In the present work, The formation of PdM(Cu, Ni, Co, Fe) bimetallic alloys on the ZnO support was investigated, together with the effect of alloy formation on the low temperature CO2 hydrogenation reaction. |
저자 | 송경호, 김학주 |
소속 | 한국에너지기술(연) |
키워드 | 촉매 및 반응공학 |
hakjukim@kier.re.kr | |
원문파일 | 초록 보기 |