학회 |
한국고분자학회 |
학술대회 |
2018년 봄 (04/04 ~ 04/06, 대전컨벤션센터) |
권호 |
43권 1호 |
발표분야 |
기능성 고분자 |
제목 |
Energy Transfer in Polymerized Diacetylene-Oligothiophenes Cocrsytals |
초록 |
The energy transfer mechanism by engineering cocrystals having well-ordered supramolecular architectures and conducting organic molecules has been widely accepted for devising molecular electronics. In this context, we have constructed highly fluorescent and polymerizable cocrystals of α-Oligothiophenes (nTs) encapsulated macrocyclic diacetylene (MCDA). The formation of orderly arranged MCDA and nTs cocrystal was confirmed by X-ray diffraction analysis. The process of energy transfer between MCDA and nTs in the co-crystals was determined by performing UV-vis and fluorescence spectral studies. The fluorescence quenching of nTs as a result of UV-induced polymerization of self-assembled MCDA demonstrates the energy transfer process in the cocrystals. |
저자 |
배광민, 허정무, 김종만
|
소속 |
한양대 |
키워드 |
Polydiacetylene; Oligothiophenes; Cocrystallizaiton; Encapsulation
|
E-Mail |
|