학회 |
한국고분자학회 |
학술대회 |
2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터) |
권호 |
38권 1호 |
발표분야 |
분자전자 부문위원회 |
제목 |
Synthesis and transistor properties of novel asymmetric oligothiophenes : the relation between structure and performance |
초록 |
A series of novel thiophene-naphthalene based three asymmetric oligomers, 5-decyl-2,2’:5’,2’’:5’’,2’’’-quterthiophene (DtT), 5-decyl-5’’-(naphthalen-2-yl)-2,2’:5’,2’’-terthiophene (D3TN), 5-(4-decylphenyl)-5’-(naphthalen-2-yl)-2,2’-thiophene (DP2TN) were synthesized by Suzuki cross-coupling reaction. Additionally, an investigation of the performance of organic field-effect transistors based on these oligomers in view of the relationship between the solid-state order and the electronic performance is described. UV-vis absorption measurements revealed that the three oligomers induced the formation of H-type aggregates. The solution-processed organic field-effect transistors were fabricated by spin-coating on octyltrichlorosilane-treated SiO2. The fabricated devices showed the field-effect mobility of 3.3 × 10-3 cm2/Vs for DtT, 1.6 × 10-2 cm2/Vs for D3TN and 3.7 × 10-2 cm2/Vs for DP2TN. |
저자 |
안태규1, 장상훈2, 황지헌1, 차효정1, 박선욱1, 김래호1, 정용진1, 권순기2, 김윤희2, 이상경2, 박찬언1
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소속 |
1포항공과대, 2경상대 |
키워드 |
유기박막트랜지스터; h-aggregation; XRD; oligomer
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E-Mail |
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