화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 기능성고분자-막분리용 고분자
제목 Synthesis of microporous polyurea networks by cross-linking copolymerization of tetrakis(4-aminophenyl)methane and 2,2’,7,7’-tetraamino-9,9’-spirobifluorene with diisocyanate
초록 Microporous polyurea networks were synthesized by cross-linking copolymerization of tetrakis(4-aminophenyl)methane and 2,2’,7,7’-tetraamino-9,9’-spirobifluorene with 1,6-diisocyanatohexane. We were able to obtain colloidal dispersions (sols) at concentrations below critical gelation point. The microporous characteristics of the networks were studied with varying the comonomer compositions. The nanopaticles obtained from the organic sol state were characterized using dynamic light scattering, atomic force microscope, and scanning electron microscope. This work was supported by a Korea Science and Engineering Foundation (KOSEF) grant. [2010-0026421]
저자 안민균1, 박지웅2
소속 1광주과학기술원, 2광주과학기술원 신소재공학과
키워드 Polyurea network; Crosslinking copolymer; Organic sol-gel process
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