화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2014년 봄 (04/30 ~ 05/02, 제주국제컨벤션센터)
권호 18권 1호
발표분야 포스터-무기재료
제목 Improvement in scratch resistance of PMMA using aluminum catalyst for organic/inorganic hybrid hard coating material
초록 Hard coating materials for improving the scratch resistance of transparent plastic substrate surface were prepared by mixing urethane acrylate, polyhedral oligomeric silsesquioxane (POSS), and modified silica sol. POSS was prepared by a sol-gel reaction of organo-trialkoxysilane. Silica sol was modified with organoalkoxysilane to form chemical bonds on a substrate. Aluminum catalyst was added to increase the degree of condensation. UV-cured organic/inorganic hybrid hard coating on a PMMA substrate resulted in a highly uniform and transparent coating layer. Condensation of sol-gel product was studied by 29Si nuclear magnetic resonance. Surface hardness of hard coating layer was evaluated by a pencil hardness test. Transmittance of hard coating was investigated by UV/Vis spectrometer. The properties of hard coating layer varied depending on the degree of condensation.
저자 황가영, 김형일
소속 충남대
키워드 Hard coating; sol-gel; hybrid material; UV curing; scratch resistance
E-Mail