화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 기능성 고분자
제목 Preparation of Microporous Polymer Networks by Heck Cross-coupling Reaction
초록 Microporous polymers have been studied for applications such as gas storage, gas separation, and catalysis. In this work, we prepared microporous polymer networks by Heck cross-coupling reaction of divinylbenzene and aryl-bromo derivatives. We used PCP Pincer Palladium(II) Complexes as a catalyst having high reactivity and regioselectivity. The morphologies and Brunauer-Emmett-Teller surface areas of the polymers were investigated. The microporous polymers carbonized at 800 oC showed enhanced BET surface areas and CO2 uptakes.
저자 이현표, 장지영
소속 서울대
키워드 microporous material; carbonization
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