| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
20권 2호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Electrochemical behavior of Co2+ in PF-6, CF3SO3-, (CF3SO2)2- and BF-4 anion containing RTILs |
| 초록 |
The Room temperature ionic liquids have wide range of scope in the electrochemical and non-electrochemical fields and access to use as green solvent in the synthesis of organic compounds. RTIL’s electrochemical properties are depends on the anion and cation moiety in the system. The electrochemical potential window of imidazolium IL is related to an anions group bounded with cation moiety, where cell potential corresponds to anion moiety like PF-6(4V), CF3SO3- (5V), (CF3SO2)-2(6V) and BF-4 (4V). The influence of RTIL’s anion moiety can able control the electrochemical behavior of the dissolved metal. With this idea, we performed the cyclic Voltammogram study on CoCl2 in 4 different RTIL contained 1-butyl-3-methylimidazolium as cation and all above mentioned species as anions. The electrochemical redox properties of Co2+/Co3+ were analyzed on different electrodes like Pt, Ti and Graphite. |
| 저자 |
G. MUTHURAMAN, K.KANNAN, 문일식
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| 소속 |
순천대 |
| 키워드 |
RTIL; PF-6; CF3SO3; (CF3SO2)2 and BF-4; electrochemical studies;
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| E-Mail |
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