화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU))
권호 20권 2호
발표분야 (국제협력) 우수 외국인 연구자 세션
제목 Energy transfer based spectral properties of TiO2 NPs impregnated co-doped Gd3++Eu3+: PVA polymer nanocomposites for luminescent Applications
초록 We have synthesized Eu3+: PVA, Gd3+: PVA, Gd3++Eu3+: PVA and Gd3++Eu3++ TiO2 nanoparticles: PVA polymer films by solution casting method. Eu3+ doped PVA polymer films displayed a red emission at 618 nm (5D0→7F2) under 396 nm (7F0→5L6) of excitation.  Upon co-doping with Gd3+ to Eu3+: PVA polymer film, it exhibits enriched red emission than singly doped Eu3+: PVA under 270 nm of excitation due to energy transfer from Gd3+ to Eu3+ ions. After dispersion of TiO2 NPs in the co-doped Gd3++Eu3+: PVA polymer films, the PL properties of Eu3+ are remarkably enhanced. Red emission of Eu3+ is significantly enhanced though an efficient ET process from Gd3+ to Eu3+ and TiO2 NPs to Eu3+. These polymer nanocomposite films could be suggested as promising candidates for red luminescent photonic devices.
저자 K Naveen Kumar1, L. Vijayalakshmi2, 강미숙1
소속 1영남대, 2NRI Institute of Technology
키워드 Gd3++Eu3++ TiO2 nanoparticles: PVA polymer composites; Red emission; Energy transfer
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