| 학회 |
한국공업화학회 |
| 학술대회 |
2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터) |
| 권호 |
17권 2호 |
| 발표분야 |
포스터-고분자 |
| 제목 |
Synthesis of PMMA-PSSQ Nanocomposites via Surface Initiated Radical Polymerization |
| 초록 |
Well-defined core-shell structured polymethylmethacylate (PMMA) grafted polysilsesquioxane (PSSQ) nanocomposites (PMMA-g-PSSQ) were synthesized via thiol-lactam initiated radical polymerization by employing a grafting from protocol. Thiol functionalized PSSQ were prepared by hydrolysis and condensation of 3-mercapropropyl-trimethoxysilane in acidic condition. Subsequently, the surface initiated polymerization was accomplished by using two component initiating system comprising thiol functionalized PSSQ(PSSQ-SH) and butyrolactam. The anchoring of PMMA onto the surface of PSSQ-SH was ascertained by 1H-NMR, GPC and XPS analyses. An improved thermal property of the polymer matrix with incorporating PSSQ was revealed by TGA study |
| 저자 |
황하수, 박인
|
| 소속 |
한국생산기술(연) |
| 키워드 |
Silsesquioxane; PMMA; Nanocomposite
|
| E-Mail |
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