| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
| 권호 |
32권 1호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
The characterization of poly(trimethylene 2,6-naphthalate) surface structure in nano-space using RA-FTIR and GIXRD methods |
| 초록 |
The structure and crystallization behavior of polymer in nano-space have attracted lots of interest over recent years. Here, we combined the RA-FTIR and GIXRD to investigate the thickness-dependent chain orientation and crystal structure of PTN with the thickness from 700nm to 50nm. RA-FTIR is a powerful tool to describe the characteristic of polymer with high resolution and sensitivity. We used polarized RA-FTIR to study the confinement effect of PTN within 100nm film during thermal-induced crystallization. And different crystal structures of PTN thin films can be identified clearly by GIXRD. PTN, shows different lamella structures when the film thickness decreases. Edge-on and flat-on lamella structures were obtained in thick and thin anisotropic PTN films separately which were consistent with the result from RA-FTIR. Furthermore, we found that PTN in ultrathin films showed less orientation and retarded crystallization which were also observed by GIXRD and RA-FTIR methods. |
| 저자 |
정미주, 이한섭, 최기운
|
| 소속 |
인하대 |
| 키워드 |
PTN chain orientation; crystallization; RA-FTIR; GIXRD
|
| E-Mail |
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