| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
20권 2호 |
| 발표분야 |
촉매_포스터 |
| 제목 |
One-pot Heterogeneous Catalytic Decarbonylation of Alcohols Using Supported PdO-doped on Silica Nanoparticle (PdO@SNP) |
| 초록 |
Palladium oxide supported on silica nanoparticles (PdO@SNP) was successfully employed for the efficient heterogeneous decarbonylation of alcohols to generate valuable products at moderate temperature in absence of any co-catalyst. The transformation of 2-napthalenemethanol to napthalene was optimised and further the decarbonylation of various benzylic, allylic, hetero-atomic and aliphatic alcohols was accomplished with excellent yields and selectivity. The PdO@SNP nanocatalyst showed a high mechanical stability since no leaching was observed in the reaction vessel. The nanocatalyst could be recycled several times for the decarbonylation of 2-napthalenemethanol |
| 저자 |
Nyanzi joseph, 김정원
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| 소속 |
강원대 |
| 키워드 |
One-pot reaction; Heterogeneous; Decarbonylation; Alcohols; Palladium oxide
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| E-Mail |
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