화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터)
권호 34권 1호
발표분야 기능성 고분자
제목 Synthesis and Electroluminescence of Polyfluorene Copolymers with Phenothiazine Derivative; Their Applications to High-Efficiency Red and White PLEDs
초록 We have synthesized a series of new fluorene-based copolymers (PFPTRs) with varying molar ratios of the low energy band-gap comonomer, BPTR. These polymers were synthesized with the aim of creating pure red-emitting-materials for use in OLEDs as well as polymers that can form the basis of efficient white-light-emitting materials. An EL device fabricated with PFPTR 1 was found to emit nearly pure red light with CIE coordinates of (0.62, 0.36), which are very close to the standard red (0.66, 0.34) demanded by the National Television System Committee. Its maximum external quantum efficiency and maximum current efficiency were 2.3% and 1.70 cd/A at 10V, respectively. Moreover, devices based on PFPTR 01 and PFPTR 025 displayed white electroluminescence with CIE coordinates of (0.27, 0.40) and (0.41, 0.37), their maxima of current efficiency and external quantum efficiency are 1.84 and 1.21 cd/A, 0.87 and 1.06 % respectively, which appear near-white to the naked eye.
저자 박무진, 심홍구
소속 한국과학기술원
키워드 fluorene; phenothiazine
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