| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Synthesis of Well-defined Photosensitive Amphiphilic Star Block Copolymer by Controlled Radical Polymerization. |
| 초록 |
Photosensitive amphiphilic star block copolymer with a porphyrine core and poly(N-isopropyl acrylamide)-b-polystyrene block copolymer arm chains (PNIPAM-b-PS) was synthesized by controlled radical polymerization (Reversible addition fragmentation chain transfer, RAFT). For this, 8 RAFT agents were introduced to photosensitive porpyrine core and polymerized styrene with AIBN. Obtained 8 arms PS star polymers with porphyrine core was then used as a macroinitiator and polymerized NIPAM with AIBN to prepare well defined PNIPAM-PS-porphyrine Photosensitive star polymers (PDI ＜ 1.3). Obtained series of the star polymers were then examined as a smart remover of BETX in aqueous solution. |
| 저자 |
조계룡1, Anuj Mittal1, 박상희1, 서명순2, 황승상1, 윤호규3, 이상협2, 백경열1
|
| 소속 |
1KIST 고분자하이브리드센터, 2KIST 물환경센터, 3고려대 |
| 키워드 |
Reversible addition fragmentation chain transfer; Photosenstive Star-Polymer; diblock copolymer; Amphiphilic; Controlled radical polymerization.
|
| E-Mail |
|
