| 초록 |
Including the action in the body as a basic example, chirality plays an important role in human life. Therefore, people have made a lot of efforts to utilize this chirality. Chiral supramolecular structures, made as one of the results of such efforts, can be used to chiral recognition, sensing, and catalysis. In this study, we synthesized the novel homochiral and heterochiral coordination polymers (CPs) using reactions between chiral organic ligands and zinc sources. In the heterochiral CPs, we can observe a chiral self-discrimination, which is not the common case. They are photochromatic and photoswitchable because of the formation of radical anions under exposure to UV light. In addition, they have been applied to photoluminescent sensing for hydrazine. Focusing on the low conductivity of them, we also tried chemiresistive sensing of protonic solvents such as methanol and ethanol. All of these approaches provide novel ways of synthesises and applications of the coordination polymers. |
