초록 |
Superabsorbent hydrogels can hold considerable amount of water, which is strongly dependent on the cross-linking density. This study focuses on the preparation of hydrogels by reweighing the effect of cross-linking density on physical properties, which provides green fabrication of bilayered hydrogels that consist of homogeneous structural motifs but show programmed responses via sequential radical polymerization. In particular, when two hydrogel layers containing different cross-linking densities are joined together, an integrated linear bilayer shows heterogeneous deformation triggered water. We monitor the linear hydrogel bilayer bending into a circle and engineer it by incorporating disperse dyes. In addition, we demonstrate an electric circuit switch using a patterned hydrogel. Anisotropic shape change of the polyelectrolyte switch closes an open circuit and lights a light-emitting diode in red. |