화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2013년 봄 (04/24 ~ 04/26, 광주 김대중컨벤션센터)
권호 19권 1호, p.68
발표분야 고분자
제목 Synthesis of Methylated Poly(1-vinylimidazole) for Alkaline Anion-exchange Membrane Fuel Cell
초록 Alkaline anion exchange membrane fuel cell (AAEMFC) is an electrochemical device that can convert the chemical energy of H2 into directly electrical current. AAEMFCs exhibit several advantages over PEMFCs, such as that they can use cheaper non-noble metal catalysts. And the oxygen reduction (ORR) under alkaline conditions is faster than in acidic conditions. Alkaline solid polymer electrolyte membranes contain positive ionic functional groups and mobile negatively charged anions. In this regard, Poly(1-vinylimidazole)(P1Vim) was synthesized by the radical polymerization of 1-vinylimidazole. In addition, quantitive methylation supplies a permanent cationic charge on the imidazole ring. These imidazolium salts exhibit high ionic conductivities, high chemical and thermal stability.
저자 박현진1, 김형준2, 표성규1
소속 1중앙대, 2한국과학기술(연)
키워드 Anion-exchange (음이온 교환막); Polymer electrolyte (고분자 전해질); Radical Polymerization (라디칼 중합); Poly(1-vinylimidazole) (폴리(1-비닐이미다졸))
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