| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO)) |
| 권호 |
21권 2호 |
| 발표분야 |
에너지저장변환_포스터 |
| 제목 |
Study on Molecular Conformation and Arrangement of CPEs as Hole Transporting Layer of Organic Optoelectronic Devices |
| 초록 |
In this study, three synthesized conjugated polymer electrolytes (CPEs) with different conjugation lengths were introduced as the hole transporting layer (HTL) of organic solar cells (OSCs) and polymer light emitting diodes (PLEDs). In order to control the dipole moment of CPEs, three different spacer units were choiced. The synthesized n-type CPEs were modified to p-type CPEs by facile oxidation process. To identify the effect on electrode work function tunability by changing molecular conformation and arrangement, we simulated density function theory (DFT) calculations of these molecules and performed ultraviolet photoelectron spectroscopy (UPS) analysis for films of indium-tin-oxide (ITO)/CPEs. Additionally, we fabricated OSCs and PLEDs by using the CPEs as the HTL. As a result, the stability and performance were enhanced in the optimized devices with PFtT-D CPE HTL compared with PEDOT:PSS HTL-based devices. |
| 저자 |
이의진1, 한용운2, 문두경2, 강진규1, 김대환1
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| 소속 |
1대구경북과학기술원, 2건국대 |
| 키워드 |
organic optoelectronic devices; stability; hole transporting layer; conjugated polymer electrolytes; molecular dipole
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| E-Mail |
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