화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 기능성 고분자
제목 Sulfonated Hyperbranched Poly(ether-ketone) Grafted MWNT
초록 During last decades, carbon nanotubes (CNTs) have been a focal point of material researches and developments due to their excellent physical, electrical and thermal properties. CNTs can be used for polymer-based composites, energy storage materials, electronic devices, biosensors and many others. Although CNTs are expected to significantly improve performances of materials, there are many issues to be addressed first. The primary issue is homogeneous dispersion and stabilization in common matrices. To provide chemical affinity with matrices, the surfaces of CNTS should be modified. Hence, multi-wall carbon nanotubes (MWNTs) were grafted with hyperbranched poly(ether-ketone) (HPEK) by in-situ polymerization of 3,5-diphenoxybenzoic acid as an AB2 monomer to afford HPEK grafted MWNT (HPEK-g-MWNT). Subsequent sulfonation with chlorosulfonic acid makes HPEK-g-MWNT hydrophilic. As a result, sulfonated HPEK-g-MWNT becomes soluble in water.
저자 손경주, 전인엽, 백종범
소속 울산과학기술대
키워드 carbon nanotubes; sulfonation; dispersion
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