학회 |
한국고분자학회 |
학술대회 |
2018년 봄 (04/04 ~ 04/06, 대전컨벤션센터) |
권호 |
43권 1호 |
발표분야 |
분자전자 부문위원회 I |
제목 |
Synthesis and Characterization of New TPD-based Polymeric Semiconductors |
초록 |
We developed and synthesized two novel polymeric semiconductor materials containing TPD units, with one of the polymers also containing thiophene (T) units and the other containing bi-thiophene (BT) units, and denoted as TPD-T and TPD-BT, respectively. TPD-T and TPD-BT were studied for bulk heterojunction organic solar cells as blends with [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM). In other words, we successfully developed two novel photoactive -conjugated copolymers, TPD-T and TPD-BT, containing TPD units via a Stille coupling polymerization approach. The TPD-T device showed a power conversion efficiency of 2.51%, higher than the 1.63% value of the TPD-BT device, and this difference was attributed to their different nanoscale bulk morphologies and hole mobilities. |
저자 |
이경석1, 천형진1, 김유진2, 황문찬1, 홍지수2, 안태규3, 권순기1, 김윤희1
|
소속 |
1경상대, 2포항공대, 3한국교통대 |
키워드 |
semiconductor materials; copolymer; OPV
|
E-Mail |
|