화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 봄 (04/04 ~ 04/06, 대전컨벤션센터)
권호 43권 1호
발표분야 분자전자 부문위원회 I
제목 Synthesis and Characterization of New TPD-based Polymeric Semiconductors
초록 We developed and synthesized two novel polymeric semiconductor materials containing TPD units, with one of the polymers also containing thiophene (T) units and the other containing bi-thiophene (BT) units, and denoted as TPD-T and TPD-BT, respectively. TPD-T and TPD-BT were studied for bulk heterojunction organic solar cells as blends with [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM). In other words, we successfully developed two novel photoactive -conjugated copolymers, TPD-T and TPD-BT, containing TPD units via a Stille coupling polymerization approach. The TPD-T device showed a power conversion efficiency of 2.51%, higher than the 1.63% value of the TPD-BT device, and this difference was attributed to their different nanoscale bulk morphologies and hole mobilities.
저자 이경석1, 천형진1, 김유진2, 황문찬1, 홍지수2, 안태규3, 권순기1, 김윤희1
소속 1경상대, 2포항공대, 3한국교통대
키워드 semiconductor materials; copolymer; OPV
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