화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU))
권호 23권 2호
발표분야 포스터_화학공정
제목 Synthesis and Process Improvement of Flurorine Substituted Cyanoacrylate UV Absorber through Eco-friendly Toluene Free Process
초록 There are ultraviolet rays that affect plastics and rubber among the various wavelengths of light, and UV absorbers are used to protect against these effects. This study deals with cyanoacrylate UV absorbers and basically removes ammonia from the process to practice eco-friendly process. In order to compare and analyze the electron donor substituents and the electron withdrawing substituents, the fluorine derivatives having the best physical properties were synthesized and analyzed. Since toluene was not used during the whole synthesis process, it was environmentally friendly. The process conditions (temperature, catalyst, solvent) of each synthesis method were changed to optimize the process to obtain high yields. As a results P-H was achieved UV absorbance of 77.6% in 317nm, color of solution of 97.5% in 460nm and 99.5% in 500nm, and heat stability of 93.5%.
저자 권지현, 이근대, 박성수, 이원기, 진영읍
소속 부경대
키워드 UVA; UVB; UV protect
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