화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO))
권호 23권 1호
발표분야 나노_포스터
제목 Application of AA'-Stacked Trilayer Hexagonal Boron Nitride for Proton Exchange Membrane Fuel Cells
초록 Hexagonal boron nitride (h-BN) and graphene have emerged as promising materials for proton exchange membranes because of their high proton conductivity and chemical stability. However, the defects and grain boundaries generated during the growth and transfer of two-dimensional materials limit their practical applicability. Here, we report the fabrication of membrane electrode assemblies using large-area single-oriented AA′-stacked trilayer h-BN, which exhibits very few defects during the growth and transfer, as a proton exchange membrane for use in fuel cell systems. The fuel cell based on AA′-stacked 3L-BN showed H2 permeation current density as low as 2.69 mA cm−2 and open circuit voltage as high as 0.958 V; this performance is much superior to those for cells based on Nafion (3.7 mA cm−2 and 0.942 V). Furthermore, the fuel cell with the AA′-stacked 3L-BN membrane almost maintained its original performance even after 100 h of an accelerated stress test at 30% RH and 90 oC.
저자 윤성인1, 서동준2, 김광우1, 김민수1, 정치영2, 윤기영2, 주상훈1, 김태영2, 신현석1
소속 1울산과학기술원, 2한국에너지기술(연)
키워드 Hexagonal boron nitride; h-BN; Proton membrane
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