| 학회 |
한국화학공학회 |
| 학술대회 |
2015년 가을 (10/21 ~ 10/23, 일산 KINTEX) |
| 권호 |
21권 2호, p.2390 |
| 발표분야 |
환경 |
| 제목 |
Electrocatalyzed oxidation of Toluene by Co(II) in pyrrolidinium cation containing room temperature ionic liquid |
| 초록 |
Room temperature ionic liquids (RTILs) are mixed ionic systems possessing organic cations and organic or inorganic anions existing in liquid state at ambient temperatures. They are widely used in many electrochemical applications such as gas sensors, catalysis, electro deposition, solar cells and batteries etc., due to their unique physic-chemical like low volatility, high thermal stability, wide electrochemical potential window and intrinsic conductivity. In the present study we have used N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([bmpyr]+[TFSI]-) as the solvent medium for the oxidation of Cobalt(II) species to generate electrochemically Co(II)/Co(III) redox couple. The electrochemically generated Co(II) was used to electro-catalyze the oxidation of toluene at various temperatures. It was observed that toluene undergoes facile oxidation in presence of Co(II) ion and converted to benzoquinone. |
| 저자 |
SUBRAMANIAN BALAJI, Kannan Karunakaran, 문일식
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| 소속 |
순천대 |
| 키워드 |
Pyrrolidinium ionic liquid; Co(II) oxidation; cyclic voltammetry; FTIR
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| E-Mail |
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| 원문파일 |
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