| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Synthesis of Functional Poly (divinylbenzene) Nanoparticles by Inter-block RAFT Polymerization |
| 초록 |
An efficient synthetic method of stable nanoparticles with PEO functionalities on the core surface was developed and one advantage of this method is that the micellization and cross-linking reactions occur in one pot, forming stable nanoparticles with functional surfaces. First, amphiphilic PEO-b-PS copolymers were synthesized by RAFT polymerization of styrene using PEO-based trithiocarbonate as macro-RAFT agent. The low molecular weight PEO-b-PS copolymer was dissolved in isopropyl alcohol where the block copolymer self-assembled as core-shell micelles, and then the core-shell interface cross-link was performed using DVB as a cross-linking agent and AIBN as an initiator. Design of the amphiphilic RAFT agent is found to be critical for the successful preparation of core-shell interface cross-linked micelle nanoparticles, because RAFT functional group inter-connects PEO and polystyrene block. The PEO functionality of the nanoparticles surface was confirmed by 1H-NMR and FT-IR. |
| 저자 |
MD. Harun-Or Rashid, Md. Daloar Hossain, 임권택
|
| 소속 |
부경대 |
| 키워드 |
Core-shell interface; cross-linked micelle; reversible addition fragmentation chain transfer. |
| E-Mail |
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