| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
포스터_고분자 |
| 제목 |
Synthesis and Characterization of Small Molecules based on Benzothiadiazole as the core and its Application in Organic Solar Cells |
| 초록 |
Small molecule acceptor materials with A1-π-A2-π-A1 (acceptor1-π-acceptor2-π-acceptor1) type of structure based on benzothiadiazole (BT) (A2) as the conjugated backbone, electron-rich thiophene (D) as the π-bridge, and end-capped by dicyanovinylindandione (IDC) (A1) groups, which are (BT-T-IDC) and (BT-T-tB-IDC), have been synthesized. The materials showed good thermal stability with the onset decomposition temperature (Td) upon 310 °C at 5 wt % loss. BT-T-IDC material has a low solubility due to its high planarity structure. In order to increase the solubility of BT-T-IDC material, t-butyl was introduced into the material. As the result, the PCE of the device based on the material with t-butyl (BT-T-tB-IDC) (1.55%) was enhanced than that of the device based on BT-T-IDC with an open-circuit voltage (VOC) of 0.88 V, a short-circuit current density (JSC) of 4.09 mA/cm2, and a fill factor (FF) of 43.0%. |
| 저자 |
Ratna dewi maduwu, 진호철, sabrina aufar salma, 이준호, 정미진, 손동환, 김주현
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| 소속 |
부경대 |
| 키워드 |
Organic solar cells; benzothiadiazole; dicyanovinylindandione; 2-(3-oxo-2; 3-dihydroinden-1-ylidene)malononitrile; 2-(5-(tert-butyl)-3-oxo-2; 3-dihydro-1H-inden-1-ylidene)malononitrile
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| E-Mail |
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