화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터)
권호 35권 1호
발표분야 분자전자 소재 및 소자(분자전자 부문위원회)
제목 Donor-Spacer-Acceptor Block Copolymer Containing Both Poly(2,7-carbazoles) (PCz) and Perylene tetracarboxydiimide (PDI)
초록 We report a straightforward synthesis toward conjugated rod-spacer-rod type block copolymer with both poly(2,7-carbazoles) (PCz) electron-donor (D) and perylene tetracarboxydiimide (PDI) electron-acceptor blocks. Two chromophores are covalently connected through sebacate units as saturated spacer. The resulting donor-spacer-acceptor type block copolymer (PCz-S-PDI) can be favorable way to limit charge recombination between donor-acceptor interfaces and to control the scale length of nanostructure formation. The PCz-S-PDI was used to produce a solar cell with the power conversion efficiency of 0.004%.
저자 이정훈, Ravi Kumar Cheedarala, 양창덕
소속 울산과학기술대
키워드 conjugated rod-spacer-rod; PCz; PDI
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