| 학회 |
한국고분자학회 |
| 학술대회 |
2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO)) |
| 권호 |
44권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Kinetic Studies of Copolymerization of Various Methacrylates by Cu(0)-Mediated Reversible Deactivation Radical Polymerization |
| 초록 |
The random copolymerization of methyl methacrylate with various methacrylate monomers was demonstrated via Cu(0)-mediated reversible deactivation radical polymerization (Cu(0)-RDRP). In kinetic studies, the apparent propagation rate constants and induction periods of the copolymerizations were estimated. The results highlight the effect of monomer structure to the kinetic parameters. Furthermore, we determined reactivity ratio based on the kinetic studies. The reactivity ratio values were varied from ideal random copolymerization pairs of methyl methacrylate and ethyl methacrylate. We further conducted comparison studies of the reactivity ratio values to the literature values from conventional free radical polymerization, highlighting the significance of our studies to gain deeper understanding of copolymerization via reversible deactivation radical polymerization. |
| 저자 |
김지수1, 김명웅1, 최종원1, 팽기욱2
|
| 소속 |
1인하대, 2성균관대 |
| 키워드 |
radical polymerization; kinetic study
|
| E-Mail |
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