| 학회 | 한국공업화학회 |
| 학술대회 | 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 26권 1호 |
| 발표분야 | [정밀화학] 지속 가능한 정밀화학기술 |
| 제목 | Radical Polar Crossover Strategy in Organic Electrosynthesis |
| 초록 | Due to the unique reactivity of open-shell intermediates, the development of catalytic transformations driven by single-electron transfer (SET) has been an area of intense research in organic chemistry. In particular, the employment of unconventional means of activation, including photoredox catalysis and electrocatalysis, has provided unique entry to single-electron reactivities and led to new solutions to challenging synthetic problems that are not readily addressed using existing tools. In this lecture, an electrochemically driven radical-polar crossover strategy for the stereo- or regioselective alkene functionalization reactions will be discussed. Compared to the precedent examples, the newly developed system obviates the need for external oxidizing agents, thus providing an operationally simple and efficient route to an array of synthetically valuable organic products. |
| 저자 | 김현우 |
| 소속 | 이화여자대 |
| 키워드 | radical polar crossover; electrosynthesis; electrocatalysis |
