화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 봄 (04/23 ~ 04/25, 창원컨벤션센터)
권호 20권 1호, p.595
발표분야 열역학
제목 A Simple Computational Method to Estimate Minimum Miscibility Pressure (MMP) for CO2 Enhanced Oil Recovery (CO2 EOR)
초록 A computational method to estimate MMP for CO2 EOR is developed based on thermodynamic calculations to describe phase behavior of CO2-crude oil multicomponent mixture. Thermodynamic analysis provides fast and effective tools to predict the miscibility of CO2 and crude oil mixtures, which is measured by  time-consuming experiments. We suggest that MMP at a reservoir temperature should correspond to the Upper Critical Solution Pressure (UCSP) at the given temperature. Since MMP is a critical property of a multicomponent mixture, its accuracy depends on the robustness of the equation of state used to model the phase behavior near the critical pressure and temperature. In this study, Predictive Peng-Robinson equation of state (PPR78 EOS) is used, where binary interaction parameters (kij) are temperature-dependent, and it lead to better approximations to phase behaviors of real mixtures. The MMP estimation based on composition data and the reservoir temperature showed a good agreement with experimental slim-tube test results within average error of 5%.
저자 Ria Ayu Pramudita1, 김연지1, 배위섭2, 권용훈2, Dadan Damayandri2, 류원선1
소속 1홍익대, 2세종대
키워드 enhanced oil recovery; minimum miscibility pressure; phase equilibrium; CO2 injection
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