화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터)
권호 25권 2호, p.1664
발표분야 에너지 환경 (Energy and Environment)
제목 Synthesis of Carbon Dots from Rice Straw and Its Application to Produce Efficient Electrocatalysts for Hydrogen Evolution Reaction
초록 We report a facile method to synthesize carbon dots (Cdots) from rice straw and then use it as a directly reducing agent as well as a stabilizer to produce Cdots@Au nanoparticles. Rice straw-derived Cdots possesses oxygenated groups, which act as an electron-donating source to reduce Au3+ to Au0. The strong Au-carbon interaction propels a high electron transfer for Cdots@Au electrocatalyst towards enhanced-performance in hydrogen evolution reaction (HER). When Cdots@Au electrocatalyst is used for the HER process, the HER activity is maintained stable for 2000 cycles. The overpotential is 150 mV at a current density of 10 mA.cm-2, which is the outstanding HER performance for Au nanoparticles as a non-Pt HER electrocatalyst.
저자 Nguyen Ngoc Anh1, Van-Toan Nguyen2, Yousuf Ali3, 최호석4
소속 1충남대, 2Department of Chemical Engineering and Applied Chemistry, 3College of Engineering, 4Chungnam National Univ.
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