화학공학소재연구정보센터
학회 한국재료학회
학술대회 2021년 가을 (11/24 ~ 11/26, 경주 라한호텔)
권호 27권 2호
발표분야 A. 전자/반도체 재료 분과
제목 Dependence of dielectric properties of 0.98BaTiO3-0.02(Ba0.5Ca0.5)SiO3 doped with Dy2O3 on preparation method of PVA binder solution
초록 Effects of the solvent composition of PVA binder on dielectric properties of 0.98BaTiO3-0.02(Ba0.5Ca0.5)SiO3 ceramics doped with x wt% Dy2O3 (0.0≤x≤0.3) were investigated. The specimens sintered at 1260℃ and/or 1320℃ for 1h showed, a single phase of a perovskite structure through the entire range of compositions. The sintered specimens showed the high relative densities above 90% and uniform grain morphologies were observed. Dieletric properties were affected by crystal structural characteristics and microstructural characteristics, which were confirmed by the X-ray Rietveld refinement analysis and SEM, respectively. Microstructural characteristics of the sintered specimens were dependent on the relative solvent ratio of ethyl alcohol to water of 10wt% PVA solution. Maximum dielectric constant (εr = 2723.3) at 1kHz was obtained for the sintered specimens with 0.1wt% Dy2O3 and prepared by the solvent composition (ethyl alcohol/water = 40/60 v/o) of 10wt% PVA solution. Moreover, the dependence of IR (insulation resistance) and dissipation factor on microstructural homogeneity were also discussed.
저자 Nak Beom Jo1, Jin Seok Baek2, Eung Soo Kim3
소속 1Department of Materials Engineering, 2Kyonggi Univ., 3Suwon 16227
키워드 BaTiO<SUB>3</SUB>-based ceramics; Binder; Structural characteristics; Microstructure; Dielectric properties
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